Statistical physics modeling study of an environmentally friendly and efficient adsorbent derived from the brown macroalgae Bifurcaria bifurcata for the removal of Bisphenol A.

The brown macroalgae Bifurcaria bifurcata was valued and used to develop a carbonaceous material activated by H2SO4 (AC-BB@H2SO4), with the goal of assessing its adsorption ability against Bisphenol A (BPA). During the adsorption experiments, the effects of the adsorbent dose, solution pH, and contact time were examined, and the results were m = 0.4 g/L, pH = 8.3, and t = 120 min, with an elimination yield of 91.6 %. With comparatively high R2 values, the pseudo-second-order kinetic model perfectly fitted the experimental data. Langmuir's model was found to be the best appropriate for describing the adsorption equilibrium of BPA on AC-BB@H2SO4. The thermodynamic findings show that BPA adsorption on AC-BB@H2SO4 was spontaneous, favorable, and endothermic in nature. Even after six cycles of reuse, regeneration testing demonstrated that our adsorbent could eliminate BPA by >50 %. The BPA adsorption mechanism's statistical physics control parameters were determined and analyzed. BPA's adsorption energies were <40 kJ/mol, indicating that the interactions between BPA and AC-BB@H2SO4 were governed by physical forces (i.e., hydrogen bonding and van der Waals and electrostatic interactions). All of these intriguing findings indicate that our carbonaceous material might have direct ramifications in the field of wastewater treatment, notably for the clearance of BPA, which is difficult to biodegrade.

Marine alga "Bifurcaria bifurcata": biosorption of Reactive Blue 19 and methylene blue from aqueous solutions.

In this study, we have investigated the removal efficiency of two organic pollutants: methylene blue (MB) and Reactive Blue 19 (RB19) dyes by using a brown marine alga abundantly available on the Moroccan coastlines called Bifurcaria bifurcata (Bif-Bcata). During the experiments that were conducted in batch mode, we have studied the effect of some parameters such as pH, Bif-Bcata mass, contact time, and initial dye concentration in order to optimize the most suitable biosorption conditions. The biosorption tests on Bif-Bcata showed that the equilibrium is reached after 15 min for both dyes MB and RB19. The optimal pH values are 5.6 and 1.0 for MB and RB19, respectively. Kinetic studies revealed that the biosorption of both dyes follows the pseudo-second-order model. The biosorption isotherms demonstrated that the Langmuir model is the most appropriate to describe the biosorption equilibrium for both dyes MB and RB19 with maximum biosorption capacities reaching 2744.5 mg/g for MB and 88.7 mg/g for RB19. According to these results, it is clear that Bif-Bcata can be considered a promising biomaterial to be used as an effective biosorbent for the elimination of cationic and anionic dyes from textile effluents.